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The Welding of Stainless Steels by Pierre-Jean Cunat Materials and Applications Series, Volume 3 T H E W E L D I N G O F S T A I N L E S S S T E E L S Euro Inox Euro Inox is the European market development association for stainless steel. Members of Euro Inox include: • European stainless steel producers • National stainless steel development associations • Development associations of the alloying element industries. The prime objectives of Euro Inox are to create awareness of the unique properties of stainless steels and to further its use in both existing applications and new markets. To achieve these objectives, Euro Inox organises conferences and seminars, and issues guidance in printed and electronic form, to enable designers, specifiers, manufacturers and end users to become more familiar with the material. Euro Inox also supports technical and market research. ISBN 978-2-87997-180-3 2-87997-087-3 Polish version 978-2-87997-177-3 Czech version 978-2-87997-178-0 Dutch version 978-2-87997-179-7 Turkish version Full members Acerinox www.acerinox.es Outokumpu www.outokumpu.com ThyssenKrupp Acciai Speciali Terni www.acciaiterni.com ThyssenKrupp Nirosta www.nirosta.de UGINE & ALZ Belgium UGINE & ALZ France Arcelor Mittal Group www.ugine-alz.com Associate members Acroni www.acroni.si British Stainless Steel Association (BSSA) www.bssa.org.uk Cedinox www.cedinox.es Centro Inox www.centroinox.it Informationsstelle Edelstahl Rostfrei www.edelstahl-rostfrei.de Institut de Développement de l’Inox (I.D.-Inox) www.idinox.com International Chromium Development Association (ICDA) www.icdachromium.com International Molybdenum Association (IMOA) www.imoa.info Nickel Institute www.nickelinstitute.org Polska Unia Dystrybutorów Stali (PUDS) www.puds.com.pl SWISS INOX www.swissinox.ch T H E W E L D I N G O F S T A I N L E S S S T E E L S The Welding of Stainless Steels Second Edition, 2007 (Materials and Applications Series, Volume 3) © Euro Inox 2001, 2007 Publisher Euro Inox Registered office: 241 route d’Arlon 1150 Luxembourg, Grand Duchy of Luxembourg Phone +352 261 03 050, Fax +352 261 03 051 Executive office: Diamant Building, Bd. A. Reyers 80 1030 Brussels, Belgium Phone +32 2 706 82 67, Fax +32 2 706 82 69 E-mail: info@euro-inox.org Internet: www.euro-inox.org Author Pierre-Jean Cunat, Joinville-le-Pont, France Acknowledgement The paragraphs marked (*) in the text are extracted from “Working with Stainless Steels”, Paris (SIRPE) 1998 Cover Photograph ESAB AB, Göteborg (S) Contents 1 General information on stainless steels 2 2 Stainless steel welding processes 3 3 Weldability of stainless steels 23 4 Selecting shielding gases for welding of stainless steels 24 5 Selecting welding consumables for welding of stainless steels 25 6 Joint preparation in arc welding 26 7 Finishing treatments for welds 28 8 Safe practices 30 9 Glossary: terms and definitions 32 Disclaimer Euro Inox has made every effort to ensure that the information presented here is technically correct. However, the reader is advised that the material contained herein is for general information purposes only. Euro Inox, its members, staff, and consultants, specifically disclaim any liability or responsibility for loss, damage, or injury, resulting from the use of the information contained in this publication. Copyright notice This work is subject to copyright. Euro Inox reserves all rights of translation in any language, reprinting, re-use of illustrations, recitations and broadcasting. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, without the prior written permission of the copyright owner, Euro-Inox, Luxembourg. Violations may be subject to legal proceeding and liable for monetary damages per infringement as well as cost and legal fees and fall under prosecution act of the Luxembourg copyright law and regulations within the European Union. 1 T H E W E L D I N G O F S T A I N L E S S S T E E L S 2 1 General Information on Stainless Steels 1.3 Austenitic - Ferritic Duplex Stainless Steels: Fe-Cr-Ni (Mo)-N The microstructure of duplex stainless steels consists of a mixture of austenite and ferrite. They exhibit characteristics of both phases with higher strength and ductility. Nitrogen is added to provide strength and also aids in weldability. They are magnetic and non-hardenable by heat treatment. Range of compositions: C ≤ 0.03% - 21% ≤ Cr ≤ 26% - 3.5% ≤ Ni ≤ 8% - (Mo ≤ 4.5%) - N ≤ 0.35% 1.4 Martensitic Stainless Steels: Fe-Cr-(Mo-Ni-V) These alloys can be heat treated to a wide range of useful hardness levels. The martensic structure obtained is magnetic. Range of compositions: C ≤ 1.2% - 11.5% ≤ Cr ≤ 17% - (Mo ≤ 1.8% - Ni ≤ 6% - V ≤ 0.2%) 1.1 Austenitic Stainless Steels: Fe-Cr-Ni (Mo) These alloys are the most popular grades of stainless steels because of their excellent formability, corrosion resistance, and weldability. All are non-magnetic in the annealed condition. Range of compositions: C ≤ 0.10% - 16% ≤ Cr ≤ 28% - 3.5% ≤ Ni ≤ 32% - (Mo ≤7%) 1.2 Ferritic Stainless Steels: Fe-Cr-(Mo) Ferritic stainless steels have a low carbon content, with chromium (and molybdenum) as major alloying elements. They are non-hardenable by heat treatment and are always magnetic. Range of compositions: C ≤ 0.08% - 10.5% ≤ Cr ≤ 30% - (Mo ≤ 4.5%) T H E W E L D I N G O F S T A I N L E S S S T E E L S 3 2 Stainless Steel Welding Processes 2.1 Electric Arc Processes 2.1.1 Processes with a Refractory Metal Electrode 2.1.1.1 Gas Tungsten Arc Welding: GTAW (*) The GTAW process, also known as the TIG (Tungsten Inert Gas) or WIG (Wolfram Inert Gas) process, is illustrated in the above figure. The energy necessary for melting the metal is supplied by an electric arc struck and maintained between a tungsten or tungsten alloy electrode and the workpiece, under an inert or slightly reducing atmosphere. Stainless steels are always welded in the DCEN (Direct Current Electrode Negative) or DCSP (Direct Current Straight Polarity) mode. In these conditions, it is the workpiece that is struck by the electrons, enhancing penetration, while the electrode, which is generally made from thoriated tungsten (2% ThO2), undergoes very little wear. If a filler metal is employed, it is in the form of either bare rods or coiled wire for automatic welding. The inert gas flow which protects the arc zone from the ambient air, enables a very stable arc to be maintained. Depending on the base material, shielding gases consist mainly of mixtures of argon (Ar), helium (He) and hydrogen (H2) (see section 4 ‘Selection of shielding gases for welding stainless steel’). 70 à 90° 20° Direction of travel Shielding gas inlet Copper support + Backing gas Filler metal Arc Shielding gas Welding power supply Torch Ceramic nozzle Refractory metal electrode Principle of manual gas tungsten-arc welding Welding power supply Shielding gas Shielding gas Water Water Plasma-forming gas Plasma-forming gas Cathode (thoriated W) Direction of travel Weld pool Plasma stream Solidified weld Workpiece H. F. T H E W E L D I N G O F S T A I N L E S S S T E E L S 4 • an excellent metallurgical quality, with a precise control of penetration and weld shape in all positions; • sound and pore-free welds • very low electrode wear • easy apprenticeship The common workpiece thickness range is 0.5 mm to 3.5 / 4.0 mm. The main advantages of this process when used on stainless steels can be summarised as follows: • a concentrated heat source, leading to a narrow fusion zone; • a very stable arc and calm welding pool of small size. Spatter is absent and because no flux is required in the process, oxidation residues are eliminated so that any final cleaning operation is very much simplified; 2.1.1.2 Plasma Arc Welding: PAW (*) Plasma welding is similar to Gas Tungsten Arc Welding (GTAW). The significant difference is that the arc plasma is constricted by a nozzle to produce a high-energy plasma stream in which temperatures between 10 000 and 20 000°C are attained. Welding processes generally employ a ‘transferred arc’ configuration, where the constricted arc is formed between the electrode and the workpiece, whereas other applications more often use a ‘non-transferred’ constricted arc. Principle of keyhole plasma welding T H E W E L D I N G O F S T A I N L E S S S T E E L S 5 Since the plasma jet is extremely narrow, it cannot provide adequate protection for the weld pool, so that it is necessary to add a larger diameter annular stream of shielding gas. The gases used both for this purpose and for forming the plasma are similar to those employed in GTAW, namely pure argon (Ar), Ar – hydrogen (H2) up to 20%, Ar-helium (He) – H2. The hydrogen-containing mixtures are recommended for welding austenitic stainless steels, but like in the case of GTAW, are be to proscribed for ferritic, martensitic and duplex grades. For the latter materials, it is recommended to add nitrogen to maintain the appropriate proportions of austenite and ferrite in the weld (see section 4 ‘Selecting shielding gases for welding stainless steels’). In manual plasma welding, where the torch is hand-held, the so-called ‘micro-plasma’ and ‘mini-plasma’ processes are employed for currents between 0.1 and 15 amperes and the ‘non-emergent jet’ technique for currents between about 15 and 100 amperes. In automatic welding, where the torch is mounted on a carriage, the so-called ‘keyhole’ process is employed. By increasing the welding current (above 100 amperes) and plasma gas flow, a very powerful plasma beam is created which can achieve full penetration in the workpiece. During welding, the hole progressively cuts through the metal with the weld pool flowing in behind to form the weld. The major advantage of the PAW process over GTAW is the remarkable stability of the arc leading to: • a ‘rigid’ arc which enables better control of power input; • greater tolerance to variations in nozzle- workpiece distance, without significant modification to the weld morphology; • a narrow heat-affected zone (HAZ) and generally faster welding speeds; • greater tolerance to faulty preparation, particularly in the case of keyhole welding. The common workpiece thickness range is: • 0.1 mm to 1.0 mm for micro-plasma and mini-plasma processes • 1.0 mm to 3.5 mm for the non-emergent jet technique • 3.5 mm to 10.0 mm for the keyhole process (in a single pass). T H E W E L D I N G O F S T A I N L E S S S T E E L S 6 2.1.2 Processes with a Fusible Electrode 2.1.2.1 Gas Metal Arc Welding: GMAW (*) In the GMAW process, also known as to MIG (Metal Inert Gas) process, the welding heat is produced by an arc struck between a continuously fed metal wire electrode and the workpiece. Contrary to the GTAW and PAW processes, the electrode is consumable, an arc being struck between the fusible filler wire and the workpiece under a shielding gas. The essential characteristics of this process are: • the use of very high current densities in the electrode wire (>90A/mm2), about 10 times higher than in the covered electrode (SMAW) process; • rapid melting of the electrode wire (melting rate of about 8 m/min) due to the high temperature of the arc, making it necessary to use an automatic wire feed system, supplied by 12 kg. spools; • stainless steels are always welded in the DCEP (Direct Current Electrode Positive) or DCRP (Direct Current Reverse Polarity) mode, the positive pole of the generator being connected to the electrode; • the welding torch is generally held manually (so-called ‘semi-automatic’ process), but for high welding powers it is fixed to a carriage (‘automatic’ process). Welding power supply Spool of filler wire Shielding gas regulator Shielding gas supply Direction of travel Workpiece Nozzle Contact tube Torch 220/380V Feed rolls Control console Command cable Current conductor Metallic sheath Solid electrode wire Shielding gas inlet Electrode feed unit including: Wire feeder: wire drive motor and feed rolls Control console: Gas electrovalve, Command relays and electronic controllers Principle of gas metal arc welding T H E W E L D I N G O F S T A I N L E S S S T E E L S 7 The mechanism of metal transfer in the arc is an important process parameter, three principle modes being distinguished: • The short-circuiting or dip transfer mode, in which the metal melts to form large droplets whose diameter is often greater than that of the electrode wire. As the droplet forms at the end of the electrode, it makes contact with the weld pool and creates a short circuit, with a sudden increase in current. The surface tension causes a pinching effect which separates the droplet from the electrode. The frequency of this phenomenon is of the order of 20 to 100 Hz, corresponding to cycle times between 0.01 and 0.05 seconds. • The globular transfer or gravity transfer mode. As in the previous case, melting occurs in the form of large droplets, which break away when their mass is sufficient to overcome surface tension forces and due to the greater arc length, fall freely before coming into contact with the weld pool. • The spray transfer mode involves current densities above a certain transition level, of the order of 200 A /mm2. The electrode melts to give a stream of fine droplets. As the current density increases further, the electrode tip becomes conical and the stream of even finer droplets is released axially. GMAW requires a shielding gas to prevent oxidation in the welding arc (see section 4 ‘Selecting shielding gases for welding stainless steels’). Argon with 2% oxygen (O2) gives a stable arc and is suitable for most applications. Argon with 3% carbon dioxide (CO2) gives about the same result. The welding speed and penetration can sometimes be increased when helium (He) and hydrogen (H2) are added to the argon + O2 or argon + CO2 shielding gas. Gases higher in CO2 (MAG process) tend to produce significant carbon pickup by the weld pool together with chromium oxidation. It is for this reason that they are not recommended. The bead size and extent of penetration, will vary according to the workpiece grade (ferritics, austenitics, etc.), the type of joint, the transfer mode and the skill of the welder. For single V joints and square butt joints welded in one run, the common workpiece thickness range is 1.0 mm to 5.0 mm. Note: The GMAW process is frequently referred to as MIG welding. Confusion often arises between MIG and MAG welding processes. In fact, in the MIG process, the oxidising nature of the shielding gas (see section ‘Selecting gases for welding stainless steels’) is negligible, whereas it is deliberately enhanced in the MAG process. However, in the GMAW / MIG process, a low percentage of oxygen (O2) or carbon dioxide (CO2) is often needed in the shielding gas (argon) to improve both arc stability and wetting by the molten metal. Typical levels are 2% O2 or 3% CO2. Higher levels of O2 or CO2 give excessive oxidation of chromium (Cr), manganese (Mn) and silicon (Si) and excessive pickup of carbon (C) in the weld pool. For example, the carbon content (% C) in the weld metal, which is 0.025% for 2% CO2 containing shielding gas, could reach 0.04% for 4% CO2. T H E W E L D I N G O F S T A I N L E S S S T E E L S 8 Example of a flux-cored electrode wire 2.1.2.2 Flux Cored Arc Welding: FCAW (*) A variant of the GMAW process is the FCAW (Flux Cored Arc Welding) process, in which the electrode wire is composed of a stainless steel sheath filled with a solid flux, whose role is similar to that of the electrode covering in the manual SMAW process. The core provides deoxidizers and slag forming materials and may provide shielding gases in the case of self-shielded FCAW electrodes. The FCAW technique combines the advantages of the SMAW method with the high productivity of an automatic or semi-automatic process due to the possibility of continuously feeding the cored wire. Compared to a conventional solid electrode, the flux provides a slag cover and enhances productivity. Thus, for a current of about 200 amperes, the deposition rate is about 100 g / min. for a solid 1.6 mm diameter wire containing 20% Cr and 10% Ni, compared to about 170 g / min for a flux-cored wire of the same diameter. This large difference is due to the fact that in the flux-cored wire, only the metal sheath conducts electricity, since the core, composed of a mixture of mineral and metal powders, possibly bound in an alkali silicate, has a high electrical resistivity. Both FCAW and GMAW have similar bead sizes. For single V joints and square butt joints welded in one run, the common workpiece thickness range is 1.0 mm to 5.0 mm. Metal sheath Core = Powdered metal, flux and slag forming materials Core Core T H E W E L D I N G O F S T A I N L E S S S T E E L S 9 transfer of metal droplets, the effective shielding of the weld pool and its wettability. The metallurgical role involves chemical exchanges between the weld pool and the slag, i.e. refining of the weld metal. The covering contains a certain amount of calcium carbonate (CaCO3) which dissociates in the arc at about 900°C, to form CaO and CO2, the latter ensuring protection of the arc zone. The following section gives a short description of the most frequently used covered-electrodes: • Rutile (titania) electrodes: Slag formation is the main shielding mechanism in rutile based electrodes. Rutile electrodes are easy to handle, ensure low spatter and produce welds with smooth Principle of the shielded metal arc welding process 2.1.2.3 Shielded Metal Arc Welding (covered Electrode): SMAW (*) Although the SMAW process, also known as the MMA (Manual Metal Arc) process is very old, since the first applications were reported by Kjelberg in 1907, it remains widely employed due to its great flexibility and simplicity of use. The electrode consists of a metal core covered with a layer of flux. The core is usually a solid stainless steel wire rod. The covering, which plays on essential role in the process, is extruded onto the core, and gives each electrode its specific ‘personality’. It serves three main functions: electrical, physical and metallurgical. The electrical function is related to initiation and stabilisation of the arc, while the physical action concerns the viscosity and surface tension of the slag, which control the Solidified slag Mixing zone Weld pool Solidified weld Covering = slag forming, flux and gas forming materials Molten metal droplets Liquid slag Direction of travel covering covering Metal core Workpiece Covered electrode T H E W E L D I N G O F S T A I N L E S S S T E E L S 10 surfaces. The slag formed during the welding operation is easy to remove • Basic (lime) electrodes: Limestone is the main constituent of basic covered electrodes due to its favourable arc-stabilizing and metallurgical characteristics. It also evolves carbon dioxide which provides a gas shield. However, a major disadvantage of limestone is its high melting point. This is counteracted by additions of fluorspar (CaF2) which helps to lower the slag melting point. Basic coverings will absorb moisture if they are left in the open air for any length of time, and special care should be taken to keep the electrode dry. 2.1.2.4 Submerged Arc Welding: SAW (*) The typical drying time is one hour at a temperature of approximately 150°C to 250°C. Rutile covered electrodes can be employed in both the AC and DC modes whereas basic (lime covered) electrodes are used essentially in the DCEP mode. The common workpiece thickness range is: 1.0 mm to 2.5 mm for single run processes 3.0 mm to 10.0 mm for a multipass technique + + + -- Direction of travel Weld pool Solidified weld Workpiece Granular flux Mixing zone Welding power supply Coil of filler wire Contact tube Solidified slag Feed rolls Filler wire Principle of the submerged arc welding process T H E W E L D I N G O F S T A I N L E S S S T E E L S 11 In the SAW process the welding heat is generated by the passage of a heavy electric current between one or several continuous wires and the workpiece under a powdered flux which forms a protective molten slag covering. The process may be either fully or semiautomatic, although in the case of stainless steels most work is done with fully automatic equipment. In the automatic process, the welding current can be very high, up to 2000 amperes per wire, leading to a large power input and consequently a heavy dilution of the base metal by the filler material. The process is suitable for butt and fillet welding in the flat position and horizontal – vertical fillet welding. The power supply is generally of the DCEP reverse polarity type, and more rarely AC, when several wires are employed simultaneously in order to avoid arc blow phenomena. For both DC and AC generators, the electrode wire pay out speed must be equal to the melting rate in order to obtain a perfectly stable arc. This is achieved by the use of feed rolls commanded by a motor reducing gear system with servo–controlled speed. For welding stainless steels, a ‘lime/fluoride’ type flux is most widely used, its typical composition being: 25% ≤ CaO + Mg O ≤ 40%, SiO2 ≤ 15%, 20% ≤ CaF2 ≤ 35%. Two forms exist, produced either by melting or bonding. Fused fluxes are produced by heating to temperatures of the order of 1600 – 1700°C, and are converted to powder form either by atomisation on leaving the melting furnace, or by crushing and screening the solidified bulk material. Bonded fluxes are produced from raw materials of appropriate grain size, bonded together with an alkali silicate binder. The mixture obtained is dried, then mechanically treated, to obtain the desired final particle size. Only part of the flux is fused during welding and the unfused material is picked up, usually by a suction hose and returned to a hopper for further use. The fused flux solidifies behind the welding zone and on cooling contracts and can be readily detached. For thicker material, welds are usually made in one or two passes, i.e. a single run on a manual backing weld, or one run from either side of the plate, but a multipass technique may also be employed. In thinner material, welds can be made in one run with the aid of a grooved backing strip. Since the SAW process is used mainly for thick austenitic stainless steel sheet, particular care must be taken to avoid the formation of sigma phase due to the use of high welding energies. This is especially the case for 25% Cr – 20% Ni alloys, but also for 18% Cr – 9% Ni grades with high ferrite contents. In multipass welding, where the temperature range 650 – 900°C is crossed several times, the risk of sigma T H E W E L D I N G O F S T A I N L E S S S T E E L S 12 phase formation is increased. Subsequent solution annealing at 1050°C is then highly recommended. In the as-delivered condition, the fluxes are perfectly dry. In order to prevent moisture pick-up, it is recommended to store the flux at a temperature about 10°C higher than that of the workshop, in an atmosphere whose relative humidity does not exceed 50%. If moisture pick-up is feared or suspected, it is useful to bake the powder at 300°C for at least two hours. The SAW process is generally used for joining heavy workpieces in the thickness range 10 – 80 mm, after the root run has been completed using another welding process. The bottom bead may also be made with the aid of a grooved backing strip. 2.1.2.5 Stud Welding: SW Stud welding is a method of attaching a metal stud to a workpiece generally in the form of a sheet or a plate. There are two distinct stud welding methods: arc welding (ARC) and capacitor discharge (CD). 1. Arc Stud Welding (ARC) involves the same basic principles and metallurgical aspects as any other arc welding procedure. The stud is placed in contact with the workpiece using a hand tool called the stud gun, and an arc is struck which melts the stud base and an area of the workpiece. Before welding, a ceramic ferrule is placed in position over the end of the stud to shield the arc and to confine the weld metal. The stud is then forced into the weld pool and held in place until the molten metal solidifies and forms a homogeneous joint. The cycle is completed in less than a second, producing a full strength joint. The expandable ferrule is broken away to expose a smooth and complete fillet at the stud base. 2. Capacitor discharge (CD) stud welding involves the same basic principles and metallurgical aspects as any other arc welding procedure. When the weld gun is activated, a special precision weld tip initiates a controlled electric arc from the welder capacitor bank which melts the end of the stud and a portion of the workpiece. The stud is held in place as the molten metal solidifies, instantly creating a high quality fusion weld. Since the entire weld cycle is completed in several milliseconds, welds can be made to thin sheet without pronounced distortion, burn-through or discoloration and with small diameter fasteners ( 9 mm and less). CD welding also permits stud welding of dissimilar metallic alloys. T H E W E L D I N G O F S T A I N L E S S S T E E L S 13 1 2 3 4 Stud and ceramic ferrule against the workpiece Stud against the workpiece Stored energy discharged and stud moves downward Stud forced into molten metal Stud rises and arc struck Control times out and stud plunges into molten steel Metal solidifies and weld is completed in a fraction of a second Metal solidifies and weld is completed in a fraction of a second Arc stud welding Capacitor discharge stud welding ARC or CD Process? The arc process is generally used for stud diameters of 6 mm and above and when welding to thicker base materials or in structural applications. The CD technique is generally used for stud diameters up to 9 mm and is employed primarily when welding to thin sheet metal. Stainless Steel Studs Most stainless steels can be stud welded. With the exception of free machining grades, austenitic stainless steels studs are most commonly used for stud welding. Stainless steel studs are currently welded to stainless steels and can also be welded to mild steel. In this case, it is essential that the carbon content of the base metal does not exceed 0.20%. T H E W E L D I N G O F S T A I N L E S S S T E E L S 14 Principle of resistance spot welding 2.2 Resistance and Induction Processes 2.2.1 Resistance Spot Welding: RSW (*) This process is still extensively used and is particularly suited to the welding of thin stainless steel sheets. Melting is induced by resistance heating due to the passage of an electric current through the workpiece materials at the joint. Five different stages are generally distinguished in the spot welding process, namely: • Positioning of the sheets to be joined • Lowering of the upper electrode and application of the clamping force • Welding with a low voltage alternating current, producing a heat energy W (joules) = R (ohms) x I2 (amperes) x t (seconds) • Holding of the clamping force or application of an additional forging force and finally • Raising of the upper electrode before proceeding to the next cycle. With regard to the electrode materials, in the case of stainless steels, the best combination of low resistivity and high mechanical strength is obtained with copper – cobalt – beryllium alloys. The electrode tips are generally in the form of a truncated cone with an open angle of 120°. Formation of the weld nugget depends on the welding current and its duration and on the clamping force applied by the electrodes. R1 R2 R3 R4 R5 I } F F F' F F Welding transformer Sheets to be joined Secondary Primary Automatic switch Contact resistance Holding F'= F Welding Clamping Positioning Forging F'> F R4 et R5 : Resistances of the workpiece sheets (depend on their resistivities) R2 : Contact resistance between the 2 sheets (depends on their surface conditions and the clamping force F) R1 et R3 : Contact resistances between the electrodes and the sheets W (joules) = R (ohms) x I (amperes) x t (seconds) R = R1 + R2 + R3 + R4 + R5 2 T H E W E L D I N G O F S T A I N L E S S S T E E L S 15 The welding parameters recommended for 18% Cr – 9% Ni austenitic stainless steel and stabilised 17% Cr ferritic grades are indicated in the following table. The parameters given in the above table must be optimised to allow for the surface condition (pickled, glazed, bright annealed, polished), which has a strong influence on the interface resistance, which in turn plays a decisive role in nugget formation. Contrary to other fusion welding processes, in resistance spot welding, the melt pool cannot be controlled visually. The only defects perceptible to the eye are an excessive electrode indentation and surface spatter. However, a simple albeit destructive inspection method is the socalled ‘peel test’, which gives a rapid indication of the quality of the spot weld. In this test, one of the welded sheets is peeled off the other so that ‘buttons’ of metal tend to be pulled from one or other of the sheets. Sheet Thickness Electrode Tip Electrode Welding Welding Time (mm) Diameter Clamping Force Current (no. of Periods) (mm) (daN) (A) 18% Cr – 9% Ni Austenitic Grades 0.5 3.0 170 3500 3 0.8 4.5 300 6000 4 2.0 6.0 650 11000 8 Stabilised 17% Cr Ferritic Grades 0.5 3.0 150 4000 3 0.8 4.5 250 7550 4 T H E W E L D I N G O F S T A I N L E S S S T E E L S 16 Principle of resistance seam welding 2.2.2 Resistance Seam Welding: RSEW (*) The principle of resistance seam welding is similar to that of spot welding, except that the process is continuous. The major difference is in the type of electrodes, which are two copper-alloy wheels equipped with an appropriate drive system. The wheel edges usually have either a double chamfer or a convex profile. Compared to spot welding, where the principal process parameters are the welding current, the heating time and the hold time, additional factors to be considered in seam welding are the use of a modulated or pulsed current and the welding speed. The welding parameters recommended for Fe-Cr-Ni austenitic grades are indicated in the following table. Welding transformer Primary Secondary Upper electrode wheel Direction of travel Workpieces Lower electrode wheel Upper electrode wheel Workpieces Lower electrode Wheel Discontinuous seam welding ContInuous seam welding (overlapping weld nuggets) Direction of travel Sheet Wheel Clamping Welding Off Time Welding Welding Thickness Thickness Force Time (periods) Current Speed (mm) (mm) (daN) (periods) (Amp) (cm/min) 0.5 3.0 320 3 2 7900 140 0.8 4.5 460 3 3 10600 120 1.5 6.5 80 3 4 15000 100 2.0 8.0 1200 4 5 16700 95 3.0 9.5 1500 5 7 17000 95 T H E W E L D I N G O F S T A I N L E S S S T E E L S 17 Basic Projection Designs In both spot and seam welding, the major advantages of electrical resistance heating are the limited modification of the microstructure in the heat affected zones, the virtual absence of surface oxidation if the sheets are correctly cooled (by streaming cold water) and the very small distortion of the sheets after welding. 2.2.3 Projection Welding: PW (*) In this process, small prepared projections on one of the two workpiece surfaces are melted and collapse when current is supplied through flat copper-alloy electrodes. The projections are formed by embossing (sheet metal parts) or machining (solid metal parts) usually on the thicker or higher electrical conductivity workpiece of the joint. The projections are shaped and positioned to concentrate the current and a large number of spot welds can be made simultaneously. Lower currents and pressures are used than for sport welding in order to avoid collapse of the projections before the opposite workpiece surface has melted. The welding time is about the same for single or multiple projections of the same design. Projection welding is especially useful for producing several weld spots simultaneously between two workpieces. Various designs of weld fasteners are available for annular projection welding applications; e.g. shoulder-studs, bolts, pins, nuts and pads. e e e e D D H H e : thickness of the sections : 0.3 mm - 3.0 mm H : projection height : 0.4 mm - 1.5 mm D : projection diameter : 1.4 mm - 7.0 mm T H E W E L D I N G O F S T A I N L E S S S T E E L S 18 Principle of the electroslag welding process 2.2.4 Electroslag Welding: ESW The electroslag welding process was developed at the E.O. Paton Welding Institute (Ukraine) in the early 1950 s. Electroslag welding is a single pass process used to produce butt joints in the vertical position. Joints thicker than 15mm (with no upper thickness limit) can be welded in one pass, and a simple squareedged joint preparation is required. The process is similar to a vertical casting operation since the molten weld metal is contained by the two workpiece plates and by a pair of cooled copper shoes. Except during startup of the electroslag operation, there is no arc. The continuously fed electrodes are melted off by electrical resistance heating as they pass through a conductive molten slag layer (slag bath). The slag bath also melts the adjacent workpiece plate edges and shields the molten metal from the atmosphere. The temperature of the bath is of the order of 1900°C. To start the electroslag process, a layer of flux is placed in the bottom of the joint and an arc is struck between the electrodes and the starting block or starting pad to provide a molten slag bath. As welding proceeds, the copper shoes and the wire feed unit are moved up the joint at speeds of the order of 30 mm/min. The metal deposition rate is about 350 g/min. The electrode wire compositions normally match those of the base metal. The most popular electrode sizes are 1.6 mm, 2.4 mm and 3.2 mm in diameter. The metallurgical structure of electroslag joints is unlike other fusion welds. The slow cooling and solidification can lead to a coarse grain structure. It is for this reason that the process is recommended only for austenitic grades. + – Oscillation Electrode Molten slag Weld pool Water cooled copper shoe Workpiece Electrode guide and current contact tube Workpiece Direction of travel Water cooled copper shoe Solidified weld metal Surface of Solidified weld Starting pad T H E W E L D I N G O F S T A I N L E S S S T E E L S 19 2.2.5 Flash Welding: FW (*) This technique is used essentially for long products, e.g. rods, bars, tubes and shaped sections. Although apparently similar to upset welding, flash butt welding is in fact quite different. Indeed, during upset welding, it has been observed that when the abutting surfaces are not in perfect contact, the current passes only in a few small areas, leading to intense local heating and rapid melting, creating arcs which violently expulse the molten metal out of the joint due to the associated magnetic fields (the flashing phenomenon). The important process parameters are the welding current and the voltage, which must be sufficient to cause flashing, the instantaneous flashing speed, which must be proportional to the metal consumption and compensated by the travel of the mobile clamps, the duration of flashing and the final upset forging stage. The roughness of the initial faying surfaces must be such that the contact points are sufficiently numerous and well distributed to produce uniform flashing across the whole of the joint area. After upset forging, the joint profile should show the characteristic three-finned profile indicative of a successful welding operation. The recommended welding parameters, as a function of section area, are given for austenitic grades in the following table. Some typical applications are: wheel rims (for bicycles) produced from flash welded rings, rectangular frames (for windows and doors),etc. F F Cracks Mobile electrode clamp Fixed electrode clamp Effect of welding parameters on the final weld profile Principle of flash welding Thickness Section Area Initial Die Final Die Material Loss Flash Time (mm) (mm2) Opening Opening (Flashing & (sec) (mm) (mm) Forging) (mm) 2.0 40 13 5 8 2.2 5.0 570 25 7 18 6.0 10.0 1700 40 15 25 17.0 T H E W E L D I N G O F S T A I N L E S S S T E E L S 20 Principle of HF induction welding 2.2.6 High Frequency Induction Welding: HFIW (*) High frequency induction welding is essentially used for making tubes from strip. The process is performed by a multiple roll forming system. On leaving the last rolling stand, the tube comprises a longitudinal slit which is closed by welding. The joint is formed by solid-solid contact, with intermediate melting, as the strip edges are brought together by a pair of horizontal rolls (squeezing rolls). Due to the skin effect, the induced HF current (140 to 500 kHz) follows the path of minimum impedance, concentrating the heating at the edges. In the case of ferritic stainless steels, this high productivity process avoids the grain coarsening phenomenon to which these grades are susceptible. In this case, welding powers between 150 and 300 kW are employed depending on the tube diameter, the welding speed varying with the machine from 50 to 90 m/min. a a HF supply Weld Apex Welding or squeesing rolls Inductor Impeder Current flow lines Tube Impeder (magnetic core) Section a a T H E W E L D I N G O F S T A I N L E S S S T E E L S 21 2.3 Radiation Energy Processes (*) 2.3.1 Laser Beam Welding: LBW The laser effect (Light Amplification by Stimulated Emission of Radiation) was discovered in the optical wavelength range by Maiman in 1958. The possibility immediately appeared of using a laser beam as a small area contact–free high intensity power source for welding applications. The continuous power levels available are particularly high for carbon dioxide lasers, although it must be remembered that the effective welding power depends on the reflectivity of the workpiece material for a given incident wavelength. The sources most widely used for welding purposes are CO2 gas lasers and solid state yttrium-aluminium garnet (YAG) lasers. YAG lasers are preferred for welding thin stainless steel sheets (< 1.5 mm) in the pulsed mode. So-called CO2 lasers are better adapted for the welding of thicker stainless steel sheets or strips (1.5 to 6.0 mm). As in high frequency induction welding (HFIW), this process is widely used for the production of longitudinally welded tubes. With a power of about 6 kW, a 2 mm thick strip of stabilised 17% Cr ferritic stainless steel can be welded at a speed of about 7 m/min, and since the thermal cycle is very brief, grain coarsening in the heat affected zone is extremely limited. Principle of CO2 (CO2 , N2 , He) laser used for welding Ar Ontladingsbuis Cooling tube Gas inlet: CO2, N2, He Gas inlet: CO2, N2, He Plane or concave mirror Diameter 20 to 100 mm Exciting electrode Vacuum pump outlet Perforated plane mirror NaCl window Argon Shielding gas (Argon) Exciting electrode Exciting electrode High voltage supply ≅ 10 to 20kV T H E W E L D I N G O F S T A I N L E S S S T E E L S 22 Principle of electron beam welding 2.3.2 Electron Beam Welding: EBW Electron beam welding uses energy from a high velocity focussed beam of electrons made to collide with the base material. With high beam energy, a hole can be melted through the material and penetrating welds can be formed at speeds of the order of 20 m/min. EBW can produce deep and thin welds with narrow heat affected zones. The depth to width ratio is of the order of 20/1. Welds are made in vacuum, which eliminates contamination of the weld pool by gases. The vacuum not only prevents weld contamination but produces a stable beam. The concentrated nature of the heat source makes the process very suitable for stainless steels. The available power can be readily controlled and the same welding machine can be applied to single pass welding of stainless steel in thicknesses from 0.5 mm to 40 mm. + +– – Wehnelt DC Supply to filament (cathode) DC Supply to wehnelt 1 to 3 kV High voltage DC power supply 15 to 150 kV Electromagnetic focusing lens Electromagnetic deflection coil Cross section of an electron beam weld Simplified representation of an electron beam machine Vacuum system Workpiece Carriage Anode Electron beam T H E W E L D I N G O F S T A I N L E S S S T E E L S 23 3 Weldability of Stainless Steels 3.1 Austenitic Stainless Steels : Fe-Cr-Ni (Mo)-(N) ➤ Structures containing a few percent of ferrite (usual case) • Insensitive to hot cracking • Good resistance to intergranular corrosion for low carbon and stabilised grades • Excellent toughness and ductility • Embrittlement can occur after long exposures between 550 and 900°C due to decomposition of the ferrite to form sigma phase ➤ Fully austenitic structures (exceptional) • Sensitive to hot cracking during solidification • Good resistance to intergranular corrosion for low carbon and stabilised grades • Excellent toughness and ductility 3.2 Ferritic Stainless Steels : Fe-Cr-(Mo-Ni-V) ➤ Semi ferritic grades: 0.04% C - 17% Cr • Sensitive to embrittlement by grain coarsening above 1150°C • Poor toughness and ductility • Sensitive to intergranular corrosion • Post-weld heat treatment at about 800°C restores the mechanical properties and intergranular corrosion resistance ➤ Ferritic grades: 0.02% C – 17-30% Cr – (Stabilised Ti, Nb) • Sensitive to embrittlement by grain coarsening above 1150°C • Satisfactory ductility and improved toughness compared to semi-ferritic grades • Generally insensitive to intergranular corrosion 3.3 Austenitic – Ferritic Duplex Stainless Steels : Fe-Cr-Ni (Mo)-N • Insensitive to hot cracking • Excellent toughness and good ductility in the range from –40% C to 275°C • Sensitive to embrittlement by sigma phase when exposed between 500 and 900°C 3.4 Martensitic Stainless Steels : Fe-Cr-(Mo-Ni-V) • Sensitive to cold cracking, depending on the carbon and hydrogen contents and residual stress levels, below about 400°C (preheating and post heating are generally recommended) • High tensile strength and hardeness Good toughness, particularly for low carbon grades T H E W E L D I N G O F S T A I N L E S S S T E E L S 24 4 Selecting Shielding Gases for Welding of Stainless Steels (1) 4.1 Influence of the Shielding Gas on: GTAW, PAW, GMAW, FCAW and LBW The choice of shielding gas has a significant influence on the following factors: • Shielding Efficiency (Controlled shielding gas atmosphere) • Metallurgy, Mechanical Properties (Loss of alloying elements, pickup of atmospheric gases) • Corrosion Resistance (Loss of alloying elements, pickup of atmospheric gases, surface oxidation) 4.2 Selection of Welding Gas • Weld Geometry (Bead and penetration profiles) • Surface Appearance (Oxidation, spatters) • Arc Stability and Ignition • Metal Transfer (if any) • Environment (Emission of fumes and gases) The interaction between the welding process and the shielding gas has been described in greater detail in § 2. (1) Hydrogen–containing mixtures must not be used for welding ferritic, martensitic or duplex stainless steels (2) For welding nitrogen–containing austenitic and duplex stainless steels, nitrogen can be added to the shielding gas Welding Process Shielding Gas Backing Gas Plasma Gas Ar Ar + H2 (tot 20 %) – (1) Ar GTAW Ar + He (tot 70 %) N2 (2) Ar + He + H2 (1) N2 + 10 % H2(1) Ar + N2 (2) PAW Idem GTAW Idem GTAW 98 % Ar + 2 % O2 97 % Ar + 3 % CO2 GMAW 95 % Ar + 3 % CO2 + 2 % H2(1) Idem GTAW 83 % Ar + 15 % He + 2 % CO2 69 % Ar + 30 % He + 1 % O2 90 % He + 7,5 % Ar + 2,5 % CO2 FCAW No No 97 % Ar + 3 % CO2 Idem GTAW 80 % Ar + 20 % CO2 LBW He Idem GTAW Ar Ar: argon; H2: hydrogen; He: helium; N2: nitrogen; CO2: carbon dioxide T H E W E L D I N G O F S T A I N L E S S S T E E L S 25 (1) AISI: American Iron and Steel Institute (2) Covered electrodes for manual metal arc welding of stainless and heat resisting steels. There are two basic flux coverings: basic (B) or lime (direct current) and rutile ( R ) or titania (direct or alternating current) (3) Wire electrodes, wires and rods for arc welding of stainless and heat-resisting steels: G for G.M.A.W., W for G.T.A.W., P for P.A.W. or S for S.A.W. (4) Tubular cored electrodes for metal arc welding with or without a gas shield of stainless and heat resisting steels 5 Suggested Welding Consumables for Welding Stainless Steels Base Material Welding Consumables (1) EN 1600 EN 12072 EN 12073 Name Number Covered Wires and Rods Flux Cored Electrodes Electrodes (3) (2) (4) X5CrNi18-10 1.4301 304 E 19 9 G 19 9 L T 19 9 L X2CrNi18-9 1.4307 304 L E 19 9 L G 19 9 L T 19 9 L X2CrNi19-11 1.4306 X5CrNiTi18-10 1.4541 321 E 19 9 Nb G 19 9 Nb T 19 9 Nb X5CrNiMo17-12-2 1.4401 316 E 19 12 2 G 19 12 3 L T 19 12 3 L X2CrNiMo17-12-2 1.4404 316 L E 19 12 3 L G 19 12 3 L T 19 12 3 L X6CrNiMoTi17-12-2 1.4571 316 Ti E 19 12 3 Nb G 19 12 3 Nb T 19 12 3 Nb X2CrNiMo18-15-4 1.4438 317 L E 19 13 4 N L G 19 13 4 L T 13 13 4 N L X10CrNi18-8 1.4310 301 E 19 9 G 19 9 L T 19 9 L X2CrNiN18-7 1.4318 301 L E 19 9 L G 19 9 L T 19 9 L X12CrNi23-13 1.4833 309 S E 22 12 G 22 12 H T 22 12 H X8CrNi25-21 1.4845 310 S E 25 20 G 25 20 T 25 20 X25CrNiMo18-15-4 1.4438 317 L E 19 13 4 N L G 19 13 4 L T 13 13 4 N L X2CrTi12 1.4512 409 E 19 9 L G 19 9 L T 13 Ti X6Cr17 1.4016 430 E 17 or 19 9 L G 17 or 19 9 L T 17 or 19 9 L X3CrTi17 1.4510 430 Ti / 439 E 23 12 L G 23 12 L T23 12 L X2CrMoTi18-2 1.4521 444 E 19 12 3 L G 19 12 3 L T 19 12 3 L X2CrTiNb18 1.4509 441 E 23 12 L G 23 12 L T 23 12 L X6CrMo17-1 1.4113 434 E 19 12 3 L G 19 12 3 L T 19 12 3 Nb X2CrNiN23-4 1.4362 – E 25 7 2 N L G 25 7 2 L T 22 9 3 N L X2CrNiMoN22-5-3 1.4462 – E 25 7 2 N L G 25 7 2 L T 22 9 3 N L X12Cr13 1.4006 410 E 13 or 19 9 L G 13 or 19 9 L T 13 or 19 9 L X20Cr13 1.4021 – E 13 or 19 9 L G 13 or 19 9 L T 13 or 19 9 L X30Cr13 1.4028 420 E 13 or 19 9 L G 13 or 19 9 L T13 or 19 9 L T H E W E L D I N G O F S T A I N L E S S S T E E L S 26 6 Joint Preparation in Arc Welding The principal basic types of joints used in arc welding are the butt, lap, corner, edge and T configurations. Selection of the proper design for a particular application will depend primarily on the following factors: • The mechanical properties desired in the weld • The type of grade being welded • The size, shape and appearance of the assembly to be welded • The cost of preparing the joint and making the weld No matter what type of joint is used, proper cleaning of the workpieces prior to welding is essential if welds of good appearance and mechanical properties are to be obtained. On small assemblies, manual cleaning with a stainless steel wire brush, stainless steel wool or a chemical solvent is usually sufficient. For large assemblies or for cleaning on a production basis, vapour degreasing or tank cleaning may be more economical. In any case, it is necessary to completely remove all oxide, oil, grease, dirt and other foreign matter from the workpiece surfaces. 6.1 GTAW and PAW The square-edge butt joint is the easiest to prepare and can be welded with or without filler metal depending on the thickness of the two pieces being welded. Part positioning for a square-edge butt joint should always be tight enough to assure 100% penetration. When welding light gauge material without adding filler metal, extreme care should be taken to avoid lack of penetration or burn through. The flange type butt joint should be used in place of the square edge butt joint where some reinforcement is desired. This joint is practical only on relatively thin material (1.5 to 2.0 mm). The lap joint has the advantage of entirely eliminating the need for edge preparation. The only requirement for making a good lap weld is that the sheets be in close contact along the entire length of the joint to be welded. Corner joints are frequently used in the fabrication of pans, boxes and all types of containers. According to the thickness of the base metal, filler metal may or may not be required to provide adequate reinforcement on all corner joints. Make sure that the parts are in good contact along the entire length of the seam. All T joints require the addition of filler metal to provide the necessary build up. When 100 per cent penetration is required, be sure that the intensity of the welding current is adequate for the thickness of the base material. Edge joints are used solely on light gauge material and require no filler metal addition. The preparation is simple but this configuration should not be used where direct tensile loads are to be applied to the finished joint, since this type of joint may fail at the root under relatively low stresses. T H E W E L D I N G O F S T A I N L E S S S T E E L S 27 6.2 GMAW For GMAW welds, the root opening as well as the V angles can frequently be reduced from those normally employed in SMAW. The amount of weld metal per unit length can thus be reduced up to 30% by providing designs which require less filler metal. When designing GMAW welds for narrow grooves, it is often necessary to employ a high current density (spray transfer). 6.3 FCAW In butt weld joints, the root openings and V angles can be reduced, often enabling a saving of the order of 40% in the amount of filler metal used in the joint. The optimum joint design will often be determined by the ease with which slag can be removed in multi-pass welds. In fillet welding, smaller sizes can be employed for the same strength. The deep penetration capacity of flux cored wire gives the same strength as the larger fillet from a SMAW electrode which has low penetrating power. By comparison with SMAW electrodes, FCAW wires offer significant cost savings in a variety of ways, such as higher deposition rates, narrower grooves and sometimes two passes before stopping for slag removal. 6.4 SAW The groove openings are reduced compared to those required by other arc processes. The weld passes are heavier than for SMAW electrodes. For open root configurations, it is often desirable to provide a flux backing held in place by a copper chill bar or by a ceramic bar. For all processes, bevelling is not required for thicknesses of 3.0 mm and less, but thicker base material should be bevelled to form a “V”, “U” or “J” groove. T H E W E L D I N G O F S T A I N L E S S S T E E L S 28 7 Finishing Treatments for Welds The need for surface finishing applies primarily to arc welds. Welds made by resistance welding processes, with the exception of flash butt welding, normally go into service as welded, or after light cleaning. On completion of an arc welding operation, the weld area and surrounding base material may be contaminated by weld spatter and oxide films, depending upon the joint type, material thickness and welding technique employed. For maximum corrosion resistance, careful attention should be given to the finishing operation in order to remove all surface contaminants and irregularities that might act as sites for corrosive attack in subsequent service. In certain applications, where considerations
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